吉林省铜镍硫化物矿床地质特征   总被引：3，自引：0，他引：3  

孙平  张成国  赵光剑 《吉林地质》2008,27(2)

吉林省是中国重要的镍成矿区,笔者基于以往的科研资料,结合目前地质勘查成果,全面总结了吉林省铜镍硫化物矿床地质特征,并指出尽管全省铜镍硫化物矿床处于不同的地质构造单元,但它们具有相同的物质来源和相似的成岩成矿作用过程。  相似文献   

铜陵新桥矿田褐铁矿矿物组成及成因     

刘诗贝  徐亮  陈平  谢巧勤  陈天虎  刘海波 《岩石矿物学杂志》2016,35(3):531-542

褐铁矿是铁帽型金矿和铁矿的重要矿产类型,但目前对其从矿物学的微观角度研究较少。本文采用粉晶X射线衍射(XRD)以及场发射扫描电镜(SEM)矿物学研究手段,对铜陵矿集区新桥矿田褐铁矿的矿物组成、微结构进行研究。根据矿物组成及微结构将新桥褐铁矿分为两种成因类型:Ⅰ型褐铁矿,该类型褐铁矿主要起源于黄铁矿矿石,矿石多具蜂窝状构造。主要组成矿物为针铁矿,次要矿物为赤铁矿,含有少量石英,针铁矿晶体长度一般介于500 nm~2μm,长度/半径比值(长径比)较大;Ⅱ型褐铁矿,由原生菱铁矿矿石风化而成,矿石多具肾状构造。矿物组成主要为针铁矿,其次为赤铁矿、锰氧化物和伊利石等粘土矿物,针铁矿晶体长度一般小于500 nm,具有较小的长径比。褐铁矿矿物学和微结构不仅可以初步确定原生矿物和矿石类型,而且对寻找铁帽金矿床也具有重要指示意义。  相似文献   

酸性矿山废水中石灰岩包壳作用研究     

雷良奇  林哲琼  莫斌吉  陈斯耐  莫家  史振环 《岩石矿物学杂志》2016,35(3):553-562

研究石灰岩包壳作用有助于深入了解酸性矿山废水(AMD)在富含石灰岩的金属硫化物尾矿中的释放机制。采用AMD滞留浸泡石灰岩颗粒试料的实验方法,研究在酸水饱和条件下石灰岩次生包壳的形成作用。研究表明,AMD的Fe含量是影响石灰岩包壳作用的主因之一。在高Fe浓度(如1 029~1 033 mg/L)的AMD中,石灰岩颗粒表面可依次沉淀富Al相、石膏、纤铁矿(吸附Zn、Cu及As等),发生石灰岩包壳/钝化作用,使溶液维持酸性;而在低Fe浓度(6.71~74.8 mg/L)的AMD中,次生包壳难以生成,石灰岩得以大量溶解释碱并充分中和溶液中的H~+,使溶液达到中性。因此,Fe硫化物含量较高(如Fe含量10.62%、S含量5.70%)的石灰岩尾矿,由于其氧化后可生成高Fe浓度的酸性水而导致石灰岩包壳作用,具有释放AMD(及重金属)的危险,应注意防控。  相似文献   

热分层效应控制的水库水体氢氧同位素特征   总被引：1，自引：0，他引：1       下载免费PDF全文

蒲俊兵  李建鸿  吴夏  袁道先  张陶 《水科学进展》2016,27(4):561-568

为掌握水库热分层与氢氧同位素空间分布的关系,研究了广西兴安县五里峡水库夏季氢氧同位素空间分布特征及影响因素。研究表明:①五里峡水库夏季出现明显的热分层,库表层至-5 m为表水层,-5 m至-20 m为温跃层,-20 m以下为底温层;②五里峡水库δ18O、δD值沿大气降水线分布,但均落在桂林市大气降水线右下方,其线性方程为δD=4.66δ18O-10.85（R2=0.76）,其斜率与全球大气降雨线（GMWL）和桂林市降雨线（CLMWL）的斜率和截距差异明显,表明五里峡水库主要由降水补给,但在补给五里峡水库前已经过了强烈的蒸发作用和水岩作用;③ δ18O、δD随水深的增加逐渐偏负,具有表水层 > 入库水体 > 温跃层 > 底温层 > 出库水体（>表示偏正）的垂向分布特征。分析认为入库水体氢氧同位素的季节变化和蒸发作用随深度增加而降低是五里峡水库夏季分层期间水体氢氧同位素垂向变化的主要影响因素。  相似文献   

云南兰坪-思茅盆地和老挝钾盐矿床物质来源新认识          下载免费PDF全文

李明慧  颜茂都  方小敏  张增杰  孙淑蕊 《高校地质学报》2016,22(1):60

云南兰坪-思茅盆地勐野井钾盐矿与泰国—老挝的钾盐矿的成矿关系被认为可能具有同源性,尤其深部热液可能是其重要的物质来源之一。针对该观点氢氧同位素证据缺乏、且深部热液到底是哪种热液尚不清楚的问题,文中根据老挝钻孔ZK2893中石盐包裹体水的氢氧同位素分析结果:δ~(18)O为-2.3‰~9.5‰,平均值为2.9‰,δD的范围为-78‰~-150‰,平均值为-108.6‰,大部分小于-90‰;在δD-δ~(18)O关系图上,数据点均在交代热液范围内,因此推断,老挝钾盐成矿的深部热液为大气降水与围岩形成的交代热液,围岩提供了重要的成矿物质。此项分析还表明老挝的交代热液温度主要集中在150℃左右,即包裹体形成的温度可能也在150℃左右,云南兰坪—思茅石盐包裹体的捕获温度为145℃左右,最高达170℃,二者比较接近,这为两地钾盐矿同源的可能性提供了新的证据。  相似文献   

Determination of Platinum‐Group Elements in Geological Samples by Isotope Dilution‐Inductively Coupled Plasma‐Mass Spectrometry Combined with Sulfide Fire Assay Preconcentration          下载免费PDF全文

Minghao Ren  Yali Sun  Christina Yan Wang  Shengling Sun 《Geostandards and Geoanalytical Research》2016,40(1):67-83

A method was developed for the determination of platinum‐group elements (PGE) in geological samples by isotope dilution‐inductively coupled plasma‐mass spectrometry combined with sulfide fire assay preconcentration. Samples were fused and PGE analytes were concentrated in sulfide buttons. The buttons were dissolved using HCl leaving PGE analytes in insoluble residues, which were digested in HNO₃ and simultaneously processed for the distillation of Os. The remaining solutions were further prepared for the purification of Ru, Rh, Pd, Ir and Pt using a tandem assembly of cation and Ln resin columns. The eluents were directly analysed by membrane desolvation‐ICP‐MS. Ruthenium, Pd, Os, Ir and Pt were determined by isotope dilution, whereas Rh was determined by conventional reference material calibration combined with ¹⁹³Ir as the internal standard element. The method was validated using a series of PGE reference materials, and the measurement data were consistent with the recommended and the literature values. The measurement precision was better than 10% RSD. The procedural blanks were 0.121 ng for Ru, 0.204 for Rh, 0.960 ng for Pd, 0.111 ng for Os, 0.045 ng for Ir and 0.661 ng for Pt, and the limits of detection (3s) were 0.011 ng g^?1 for Ru, 0.008 ng g^?1 for Rh, 0.045 ng g^?1 for Pd, 0.009 ng g^?1 for Os, 0.006 ng g^?1 for Ir and 0.016 ng g^?1 for Pt when a test portion mass of 10 g was used. This indicates that the proposed method can be used for the determination of trace amounts of PGE in geological samples.  相似文献   

Growth of monodisperse,submicron aerosol particles exposed to SO2, H2O2, and NH3     

A. Gupta  D. Tang  P. H. McMurry 《Journal of Atmospheric Chemistry》1995,20(2):117-139

The growth of monodisperse particles (0.07 to 0.5 µm) exposed to SO₂ (0–860 ppb), H₂O₂ (0–150 ppb) and sometimes NH₃ (0–550 ppb) in purified air at 22 °C at relative humidities ranging from 25 to 75% were measured using the Tandem Differential Mobility Analyzer technique. The experiments were performed in a flow reactor with aqueous (NH₄)₂SO₄ and Na₂SO₄ droplets. For (NH₄)₂SO₄ droplets the fractional diameter growth was independent of size above 0.3 µm but decreased with decreasing size below that. When NH₃ was added the fractional growth increased with decreasing size. Measurements were compared with predictions of a model that accounts for solubility of the reactive gases, the liquid phase oxidation of SO₂ by H₂O₂, and ionic equilibria. Agreement between measured and predicted droplet growth is reasonable when the ionic strength effects are included. Theory and experiments suggest that NH₃ evaporation is responsible for the decrease in relative growth rates for small aqueous ammonium sulfate particles. The observed droplet growth rates are too slow to explain observed growth rates of secondary atmospheric sulfate particles.  相似文献   

硫化氢、相态烃和自然电位法综合测量勘查油气田方法     

李生郁  徐丰孚 《物探与化探》1995,19(3):172-177

经近几年试验,我们提出用土壤吸附硫化氢气体作指标,勘查油气田新方法.并将它和相态烃法、自然电位法相配合,在已知油气田开展了试验,取得令人十分满意的效果.油气藏中含有大量硫化氢气体及含硫有机化合物.油气垂直微渗漏到近地表时,硫化物气体也随伴而至.运移过程中,硫化氢气体及含硫化合物在细菌及氧气作用下会发生一系列复杂的化学变化,如生成硫酸盐等,但经已知油气田试验结果表明,在油气藏上方近地表土壤中仍保留有明显的硫化氢气体异常,而且异常形态有一定的模式,有环状、半环状、片部和带状等不同形态.异常均和下伏油气藏或断裂构造相吻合,表明硫化氢气体测量法是勘查油气田的有效方法.更引人注目的是,它和相态烃、自然电位异常吻合的很好,异常均出现在油藏上方,表明综合使用这三种方法将会取得更好的找油气效果.  相似文献   

胶东金成矿区岩石氧氢同位素地球化学背景初探   总被引：5，自引：1，他引：5  

陈振胜  张理刚  刘敬秀 《岩石矿物学杂志》1995,14(3):211-218

本文对胶东区域与金矿有关的各主要地质体氧氢同位素组成背景进行研究，给出了燕山早期“玲珑”中粗粒二长花岗岩（滦家河型花岗岩）氧氢同位素背景值为δ１８Ｏ＝７．８％，δＤ＝－１１０‰；燕山晚期郭家岭（型）斑状花岗闪长岩背景值为δ１８）＝１０．０‰；昆嵛山复式岩基背景值为δ１８Ｏ＝８．５‰，δＤ＝－９０‰。胶东群变质岩各岩性段δ１８Ｏ＝５．１－１１．３‰，δＤ＝－８１－－９６‰，表明其源岩既有幔源中基性组  相似文献   

白银厂铜－多金属矿床氢、氧同位素组成特征及蚀变岩氧同位素的找矿意义     

《西北地质科学》1995,(2)

  相似文献